Cadmium

Cd CAS: 7440-43-9 Elements

Cadmium is a soft, silvery-white transition metal, atomic number 48. Highly toxic heavy metal and carcinogen. Mainly occurs as a by-product of zinc smelting. Historically used in n…

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Caesium

Cs CAS: 7440-46-2 Elements

Caesium is a soft, gold-coloured alkali metal, atomic number 55. Has the lowest ionisation energy and electronegativity of any stable element. The caesium atomic clock defines the …

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Calcium

Ca CAS: 7440-70-2 Elements

Calcium is a soft, grey alkaline earth metal, atomic number 20. Fifth most abundant element in Earth crust. Essential for life - major component of bones, teeth, shells. Calcium io…

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Californium

Cf Elements

Californium is a synthetic radioactive actinide and a very strong neutron emitter. It was first produced at the University of California, Berkeley in 1950. It has practical uses as…

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Calorie

The calorie (cal) is a unit of energy defined as the heat needed to raise the temperature of 1 gram of water by 1°C at 15°C. The nutritional Calorie (kcal) equals 1000 calories. In…

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Calorimeter

q = C_cal × ΔT; C_cal determined by combustion of standard (e.g., benzoic acid)

A calorimeter is an insulated device used to measure the heat released or absorbed during a chemical reaction, physical change, or combustion. Common types include the coffee-cup c…

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Canal Ray

Canal rays (also called anode rays or positive rays) are beams of positive ions produced in a discharge tube by removing electrons from gas atoms. They travel in the opposite direc…

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Capillary

h = 2γ cosθ / (ρgr)

A capillary is a very narrow tube, typically with an internal diameter of less than 1 mm, used in chemistry for capillary action, capillary electrophoresis, and melting point deter…

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Capillary Action

h = 2γ cosθ / (ρgr)

Capillary action (capillarity) is the spontaneous rise or fall of a liquid in a narrow tube or porous material due to the interplay of adhesive forces (between liquid and tube) and…

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Carbanion

R⁻ (carbanion; carbon bears negative charge)

A carbanion is a carbon-containing anion in which the carbon bears a negative charge, meaning it has three bonds and an unshared pair of electrons. Carbanions are important reactiv…

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Carbon

C CAS: 7440-44-0 Elements

Carbon is a non-metal, atomic number 6, forming the basis of all known life. Allotropes include diamond, graphite, graphene, and fullerenes. Forms more compounds than any other ele…

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Carbonium Ion

R⁺ or R₃C⁺ (carbocation; carbon bears positive charge)

A carbonium ion (carbocation) is a positively charged carbon-containing ion in which a carbon atom bears a positive charge and has only three bonds. Carbocations are important reac…

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Carcinogen

A carcinogen is a substance, mixture, or radiation that promotes carcinogenesis—the formation of cancer. Chemical carcinogens may act by directly damaging DNA (genotoxic carcinogen…

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Catalyst

Ea reduced via alternative pathway; rate = k[A]^m[B]^n

A catalyst is a substance that increases the rate of a chemical reaction without being consumed in the process, by providing an alternative reaction pathway with a lower activation…

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Catenation

C-C bond formation: Cₙ → Cₙ chains; e.g., carbon: C-C-C-...

Catenation is the ability of atoms of the same element to form long chains or ring structures by bonding with one another. Carbon exhibits catenation to an exceptional degree, form…

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Cathode

Ox + ne⁻ → Red

The cathode is the electrode at which reduction occurs in an electrochemical cell. In an electrolytic cell, the cathode is connected to the negative terminal of the power source, a…

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Cathode Ray Tube

½mv² = eV

A cathode ray tube (CRT) is an evacuated glass tube in which electrons (cathode rays) emitted from a heated cathode are accelerated by an electric field and deflected by electric o…

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Cathodic Protection

Zn → Zn²⁺ + 2e⁻ (sacrificial anode)

Cathodic protection is a technique used to prevent corrosion of metal structures by making them the cathode of an electrochemical cell. This is achieved either by connecting the st…

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Cation

M^n+

A cation is a positively charged ion formed when an atom or molecule loses one or more electrons. Cations are attracted to the negatively charged cathode during electrolysis. Metal…

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Cell Potential

E_cell = E_cathode − E_anode; ΔG = −nFE_cell

Cell potential (electromotive force, EMF) is the voltage or electrical potential difference between the cathode and anode of an electrochemical cell. It is measured in volts and re…

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Central Atom

MLₙ

The central atom in a molecule or ion is the atom that is bonded to more atoms than any other, forming the core of the molecular structure. In Lewis structures and VSEPR theory, th…

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Cerium

Ce CAS: 7440-45-1 Elements

Cerium is a soft, silvery, ductile rare earth metal, atomic number 58. Most abundant lanthanide. Pyrophoric as powder or shavings - sparks when struck (used in lighter flints). Cer…

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Chain Reaction

X• + RH → R• + HX; R• + X₂ → RX + X•

A chain reaction is a self-sustaining sequence of reactions in which one of the products or by-products causes subsequent reactions of the same kind. In nuclear chemistry, a chain …

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Chain Termination Step

R• + R• → R-R; R• + X• → RX

The chain termination step is the final step in a free-radical chain reaction mechanism in which two radicals combine to form a stable non-radical product, ending the chain. Common…

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Charles's Law

V₁/T₁ = V₂/T₂ (at constant P and n); V/T = k

Charles's Law states that at constant pressure, the volume of a fixed amount of ideal gas is directly proportional to its absolute temperature (V ∝ T, or V/T = constant). First pub…

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Chemical Bonds

Chemical bonds are the attractive forces holding atoms together in compounds and molecules. The main types are ionic bonds (electrostatic attraction between oppositely charged ions…

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Chemical Change

A chemical change (chemical reaction) is a process that results in the transformation of one or more substances into different substances with new chemical compositions and propert…

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Chemical Equation

aA + bB → cC + dD (balanced; law of conservation of mass)

A chemical equation is a symbolic representation of a chemical reaction showing the reactants on the left and products on the right, separated by an arrow. Balanced chemical equati…

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Chemical Equilibrium

K_eq = [C]^c[D]^d / ([A]^a[B]^b) at equilibrium; ΔG° = −RT ln K

Chemical equilibrium is the state in a reversible reaction where the rate of the forward reaction equals the rate of the reverse reaction, so that the concentrations of reactants a…

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Chemical Hygiene Officer (CHO)

A Chemical Hygiene Officer (CHO) is a person designated in a laboratory to develop and implement the chemical hygiene plan, ensure compliance with safety regulations, and provide g…

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Chemical Hygiene Plan (CHP)

A Chemical Hygiene Plan (CHP) is a written programme required by OSHA for laboratories working with hazardous chemicals. It outlines the specific work practices, procedures, and po…

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Chemical Kinetics

Rate = k[A]^m[B]^n; k = Ae^(-Ea/RT) (Arrhenius equation)

Chemical kinetics is the branch of physical chemistry concerned with the rates of chemical reactions and the factors that influence them, including concentration, temperature, cata…

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Chemical Periodicity

Chemical periodicity refers to the recurring trends in chemical properties of elements as atomic number increases across the periodic table. Periodic trends include atomic radius, …

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Chlorine

Cl2 CAS: 7782-50-5 Elements

Chlorine is a yellow-green diatomic halogen gas, atomic number 17, with pungent suffocating odour. Powerful oxidising agent and disinfectant. Used as chemical warfare agent in WWI.…

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Chromium

Cr CAS: 7440-47-3 Elements

Chromium is a hard, lustrous transition metal, atomic number 24. Famous for its corrosion resistance and bright finish in electroplating. Chromium(III) compounds are relatively saf…

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Cis

Cis is a Latin prefix meaning "on the same side", used in chemistry to describe geometric isomers in which identical or similar substituents are on the same side of a double bond o…

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Cis-Trans Isomerism

Cis-trans isomerism (geometric isomerism) occurs when atoms or groups cannot rotate freely due to a double bond or ring structure, resulting in compounds with the same molecular fo…

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Clay

Al₂Si₂O₅(OH)₄

Clay is a naturally occurring fine-grained mineral material composed mainly of phyllosilicate minerals with layered structures. Clays are important in chemistry as ion-exchange mat…

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Cloud Chamber

A cloud chamber is a particle detector consisting of a sealed container with a supersaturated vapour of water or alcohol. When charged particles (such as alpha or beta particles) p…

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Cobalt

Co CAS: 7440-48-4 Elements

Cobalt is a hard, lustrous, silver-grey transition metal, atomic number 27. Used since antiquity to produce blue colour in glass and ceramics (cobalt blue). Essential trace element…

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Coefficient of Expansion

α = (1/L)(dL/dT); β = (1/V)(dV/dT) ≈ 3α

The coefficient of thermal expansion is a measure of how much a material expands per degree of temperature increase. For gases, the volume coefficient of expansion at constant pres…

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Cohesive Forces

Cohesion ∝ γ (surface tension); W_cohesion = 2γ

Cohesive forces are the intermolecular attractive forces between like molecules in a substance. These forces are responsible for surface tension and the tendency of liquids to mini…

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Coke

Coke is a solid carbonaceous material produced by the destructive distillation (coking) of coal in the absence of air. It consists mainly of carbon with small amounts of hydrogen, …

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Colligative Properties

ΔT_b = K_b·m; ΔT_f = K_f·m; Π = MRT; ΔP/P° = x_solute (Raoult)

Colligative properties are properties of solutions that depend on the number of solute particles (molecules or ions) rather than on the nature of the solute. The four main colligat…

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Collision Theory

Δ[A]/Δt = k[A]^m or reaction rate ∝ Z × f (collision frequency × fraction effective)

Collision theory explains chemical reaction rates by proposing that reactions occur only when reactant molecules collide with sufficient energy (greater than or equal to the activa…

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Colloid

A colloid (colloidal dispersion) is a mixture in which particles of one substance (1–1000 nm in size) are dispersed throughout another but not dissolved. Colloids differ from true …

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Combination Reaction

A + B → AB (synthesis); e.g., 2Mg + O₂ → 2MgO

A combination reaction (synthesis reaction) is a reaction in which two or more substances combine to form a single product. The general form is A + B → AB. Examples include iron re…

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Combustible

Flash point 60–93°C

A combustible substance is one capable of burning in oxygen to produce heat and light. In regulatory contexts, combustible liquids typically have flash points above 37.8°C (100°F),…

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Common Ion Effect

The common ion effect is the decrease in solubility of a sparingly soluble salt when a solution already containing one of its ions is added. For example, the solubility of AgCl dec…

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Complex Ions

[ML_n]^x+; stability: β_n = [ML_n]/([M][L]^n)

Complex ions (coordination ions) consist of a central metal ion bonded to a number of ligands (molecules or anions with lone pairs) through coordinate (dative) covalent bonds. The …

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Composition Stoichiometry

mass% A = (mass A / total mass) × 100; mole% = (moles A / total moles) × 100

Composition stoichiometry involves calculating the quantitative relationships between elements in a compound, expressed as percentages by mass or mole ratios. It uses the chemical …

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Compound

Composed of ≥2 elements in fixed ratio; e.g., H₂O, NaCl, CaCO₃

A compound is a pure substance consisting of two or more different elements chemically bonded together in a fixed ratio by mass. Compounds have properties different from their cons…

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Compressed Gas

PV = nRT

A compressed gas is any gas stored under pressure in a cylinder or container. Compressed gases include oxygen, nitrogen, hydrogen, acetylene, and carbon dioxide cylinders used in l…

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Concentration

C = n/V (mol/L) or mass/volume (g/L) or ppm (mg/L)

Concentration is the amount of solute dissolved in a given volume or mass of solvent or solution. Common units include molarity (mol/L), molality (mol/kg), mass percent (%), and pa…

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Condensation

Gas → Liquid: ΔH_cond = −ΔH_vap (exothermic)

In chemistry, condensation refers to two related phenomena: (1) a phase change in which a vapour converts to a liquid by releasing heat, and (2) a condensation reaction (condensati…

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Condensed Phases

Condensed phases are the solid and liquid states of matter, as distinct from the gaseous state. In condensed phases, particles are in close contact and intermolecular forces are si…

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Condensed States

Condensed states refer to the solid and liquid phases of matter in which atoms or molecules are closely packed together, in contrast to the vapour phase. The term is often used int…

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Conduction Band

Band gap: E_g; conduction band above valence band; metals: E_g = 0

The conduction band is the range of electron energies in a solid at which electrons can move freely and conduct electricity. In conductors (metals), the conduction band overlaps wi…

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Conformations

Described by dihedral angle φ; Newman projections; staggered vs eclipsed

Conformations are the different three-dimensional arrangements of atoms in a molecule that arise from rotation about single bonds, without breaking any bonds. In cyclohexane, the m…

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Conjugate Acid-Base Pair

pKa + pKb = pKw = 14

A conjugate acid-base pair consists of two species related by the gain or loss of a single proton (H⁺). The conjugate base is formed when an acid loses a proton; the conjugate acid…

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Conjugated Double Bonds

Alternating C=C-C=C; delocalisation extends over π system: λ_abs > isolated alkene

Conjugated double bonds are alternating single and double bonds in a molecule, creating a system of overlapping p orbitals in which pi electrons are delocalised across multiple ato…

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Contact Process

2SO₂+O₂⇌2SO₃ (V₂O₅, 450°C); SO₃+H₂SO₄→H₂S₂O₇+H₂O→2H₂SO₄

The Contact Process is the industrial method for manufacturing sulfuric acid (H₂SO₄). It involves: (1) burning sulfur or roasting metal sulfides to form SO₂, (2) catalytic oxidatio…

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Continuous Spectrum

A continuous spectrum contains all wavelengths of electromagnetic radiation within a range, appearing as a rainbow of colours with no gaps. It is produced by hot dense objects (sol…

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Control Rods

¹⁰B + n → ⁷Li + ⁴He

Control rods are neutron-absorbing rods inserted into a nuclear reactor to regulate the rate of the fission chain reaction. Made of materials with high neutron-absorption cross-sec…

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Coordinate Covalent Bond

L: → M (donor-acceptor bond; also called dative bond)

A coordinate covalent bond (dative bond) is a covalent bond in which both electrons in the shared pair are donated by the same atom, called the donor. The atom accepting the electr…

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Coordination Compound or Complex

[ML_n]^x; IUPAC name: [ligands alphabetically, metal, charge]

A coordination compound (or complex) consists of a central atom or ion (usually a transition metal) surrounded by a set of ligands bonded to it through coordinate covalent bonds. T…

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Coordination Isomers

Coordination isomers are isomers of coordination compounds in which the ligands are distributed differently between the cationic and anionic parts of the coordination complex. For …

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Coordination Number

CN = number of donor atoms bonded to central metal; common: 2, 4, 6

The coordination number in a coordination compound is the number of donor atoms (from ligands) directly bonded to the central metal ion. Common coordination numbers are 2 (linear),…

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Coordination Sphere

[MLₙ]^x (inner sphere)

The coordination sphere of a complex consists of the central metal atom or ion together with all ligands directly bonded to it. It is usually enclosed in square brackets in the for…

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Copernicium

Cn Elements

Copernicium is a synthetic radioactive transactinide element named after Nicolaus Copernicus. It may be a gas at room temperature due to relativistic effects. First synthesised in …

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Copper

Cu

Copper (Cu, atomic number 29) is a soft, malleable, ductile metal with high electrical and thermal conductivity. It was one of the first metals used by humans. Copper forms +1 (cup…

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Copper

Cu Elements

Copper is a ductile, malleable transition metal with excellent electrical and thermal conductivity. One of the few naturally occurring metallic elements, copper has been used by hu…

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Corrosion

Fe → Fe²⁺ + 2e⁻; O₂ + 2H₂O + 4e⁻ → 4OH⁻

Corrosion is the gradual destruction of a material (usually a metal) by chemical reaction with its environment, particularly oxidation by oxygen and moisture. The most familiar exa…

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Coulomb

F = kq₁q₂/r² (Coulomb's law); 1 C = charge of ~6.242 × 10¹⁸ protons

The coulomb (C) is the SI unit of electric charge, equal to the charge transported by a current of one ampere in one second. In Faraday's laws of electrolysis, one faraday (96,485 …

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Coulometry

Q = ∫I dt; n = Q/(nF)

Coulometry is an electroanalytical method that measures the quantity of charge (in coulombs) required to completely convert an analyte from one oxidation state to another. Using Fa…

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Covalent Bond

A:B (shared electron pair) | e.g., H₂: H−H, H₂O: H−O−H

A covalent bond is a chemical bond formed by the sharing of one or more pairs of electrons between two atoms, typically between non-metal atoms. Single bonds share one pair, double…

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Covalent Compounds

Covalent compounds are substances whose atoms are held together by covalent bonds rather than ionic bonds. They consist of discrete molecules (molecular compounds) or extended cova…

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Critical Mass

m_crit = π²D/(νΣ_f) for sphere; depends on geometry and material

Critical mass is the minimum mass of fissile material (such as uranium-235 or plutonium-239) needed to sustain a self-propagating nuclear chain reaction. If the mass is below criti…

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Critical Point

The critical point of a substance is the temperature and pressure above which the distinction between liquid and vapour phases disappears, forming a supercritical fluid. At the cri…

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Critical Pressure

Critical pressure is the minimum pressure required to liquefy a gas at its critical temperature. Above the critical temperature, no amount of pressure can liquefy the gas. Critical…

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Critical Temperature

Critical temperature is the temperature above which a gas cannot be liquefied by applying pressure alone, regardless of how high the pressure is. Below the critical temperature, su…

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Crystal Field Stabilization Energy

CFSE = Δ_oct × [(-0.4)(t₂g electrons) + (0.6)(eg electrons)] for octahedral

Crystal Field Stabilization Energy (CFSE) is the stabilisation energy gained by a transition metal complex due to the splitting of d orbitals in a crystal field (ligand field). Ele…

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Crystal Field Theory

Δ_oct (octahedral splitting); Δ_tet = (4/9)Δ_oct (tetrahedral splitting)

Crystal Field Theory (CFT) is a model that describes the electronic structure of transition metal complexes by considering the effect of a surrounding array of negative charges (li…

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Crystal Lattice

Described by Bravais lattice; unit cell vectors a, b, c and angles α, β, γ

A crystal lattice is the regular, three-dimensional arrangement of atoms, ions, or molecules in a crystalline solid. Lattice points represent the positions of particles and are des…

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Crystal Lattice Energy

U = −Mz₊z₋e²NA / (4πε₀r₀)(1 − 1/n); Born-Landé equation

Crystal lattice energy (lattice enthalpy) is the energy released when one mole of a crystalline ionic compound is formed from its gaseous ions at infinite separation, or equivalent…

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Crystalline Solid

nλ = 2d sinθ (Bragg)

A crystalline solid is a solid in which the particles (atoms, ions, or molecules) are arranged in a highly ordered, repeating three-dimensional pattern called a crystal lattice. Cr…

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Curie (Ci)

1 Ci = 3.7 × 10¹⁰ disintegrations per second (dps)

The curie (Ci) is a non-SI unit of radioactivity, defined as the amount of a radioactive substance that undergoes 3.7 × 10¹⁰ disintegrations per second (the activity of 1 gram of r…

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Curium

Cm Elements

Curium is a transuranic radioactive actinide named in honour of Pierre and Marie Curie. It was the third transuranic element to be discovered. Curium-244 is used as an alpha-partic…

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Cyclotron

f = qB/(2πm)

A cyclotron is a type of circular particle accelerator in which charged particles are accelerated using alternating electric fields and kept on a spiral path by a static magnetic f…

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About Chemicals Starting With C

This page lists all chemicals in our database beginning with the letter C. Each entry provides the chemical formula, CAS registry number, physical and chemical properties, common uses, and safety information. Use the alphabetical navigation above to browse other letters, or use the search function to find a specific chemical quickly.

Our chemical glossary covers acids, bases, salts, organic compounds, inorganic compounds, solvents, and many more categories. Click on any chemical name to view its full detailed profile.