C

Critical Temperature

Quick Reference
Also Known AsT_c, gas critical temperature, liquefaction temperature limit

What is Critical Temperature?

Critical temperature is the temperature above which a gas cannot be liquefied by applying pressure alone, regardless of how high the pressure is. Below the critical temperature, sufficient pressure will cause liquefaction. For practical gas liquefaction, gases must be cooled below their critical temperatures. For oxygen Tc = −118.6°C, for nitrogen Tc = −147°C.

Properties & Characteristics

Critical temperature (T_c) is the temperature above which a gas cannot be liquefied by applying pressure alone, regardless of how high the pressure becomes. Below T_c, sufficient pressure can condense a vapour to a liquid; above T_c, only a supercritical fluid exists. T_c values: CO₂ = 31.1°C, O₂ = −118.6°C, N₂ = −147°C, H₂O = 374°C. T_c correlates with intermolecular forces: stronger forces → higher T_c.

Uses & Applications

Critical temperature governs whether a gas can be stored as a liquid at ambient temperatures (CO₂, propane, ammonia can be liquefied; O₂, N₂, H₂ require cryogenic cooling). This determines storage and transport requirements for industrial gases.

Safety Information

Gases with T_c below room temperature (O₂, N₂, H₂, He) must be stored in cryogenic vessels or high-pressure cylinders. Liquid oxygen stored in cryogenic tanks is a powerful oxidiser hazard. Knowledge of T_c is essential for correct gas storage system design.

Always consult the SDS/MSDS before handling any chemical. This information is for educational purposes only.

Key Facts

Term Critical Temperature
Synonyms T_c, gas critical temperature, liquefaction temperature limit

Frequently Asked Questions

Critical temperature is the temperature above which a gas cannot be liquefied by applying pressure alone, regardless of how high the pressure is. Below the critical temperature, sufficient pressure will cause liquefaction. For practical gas liquefaction, gases must be cooled below their critical temperatures. For oxygen Tc = −118.6°C, for nitrogen Tc = −147°C.

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