C

Cathode

Ox + ne⁻ → Red
Quick Reference
Formula / NotationOx + ne⁻ → Red
Also Known AsNegative electrode (electrolytic), reduction electrode, positive terminal (galvanic)

What is Cathode?

The cathode is the electrode at which reduction occurs in an electrochemical cell. In an electrolytic cell, the cathode is connected to the negative terminal of the power source, and cations migrate towards it to gain electrons. In a galvanic (voltaic) cell, the cathode is the positive electrode. The word derives from the Greek for "downward path".

Formula & Notation

Ox + ne⁻ → Red

Other Names / Synonyms: Negative electrode (electrolytic), reduction electrode, positive terminal (galvanic)

Properties & Characteristics

The cathode is the electrode at which reduction occurs in an electrochemical cell. In electrolytic cells, the cathode is connected to the negative terminal of the power source. In galvanic cells, the cathode is the positive terminal. Metal ions are deposited at the cathode during electroplating: Cu²⁺ + 2e⁻ → Cu. In the electrolysis of brine, hydrogen is evolved at the cathode: 2H₂O + 2e⁻ → H₂ + 2OH⁻.

Uses & Applications

Cathodes are essential in electroplating, electrolytic refining, the chlor-alkali process, aluminium smelting (Hall-Héroult process), lithium-ion batteries, and fuel cells. The cathode material affects selectivity, overpotential, and efficiency of the electrochemical process.

Safety Information

Cathodes producing hydrogen gas create explosion risks (H₂ is flammable, 4-75% in air). Ensure adequate ventilation in electrochemical laboratories. Alkali metal deposition at cathodes (molten salt electrolysis) is highly reactive and must be handled under inert atmosphere.

Always consult the SDS/MSDS before handling any chemical. This information is for educational purposes only.

Key Facts

Term Cathode
Formula Ox + ne⁻ → Red
Synonyms Negative electrode (electrolytic), reduction electrode, positive terminal (galvanic)

Frequently Asked Questions

The cathode is the electrode at which reduction occurs in an electrochemical cell. In an electrolytic cell, the cathode is connected to the negative terminal of the power source, and cations migrate towards it to gain electrons. In a galvanic (voltaic) cell, the cathode is the positive electrode. The word derives from the Greek for "downward path".

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