C

Crystal Lattice Energy

U = −Mz₊z₋e²NA / (4πε₀r₀)(1 − 1/n); Born-Landé equation
Quick Reference
Formula / NotationU = −Mz₊z₋e²NA / (4πε₀r₀)(1 − 1/n); Born-Landé equation
Also Known AsLattice energy, ionic crystal energy, Born-Landé lattice energy, U

What is Crystal Lattice Energy?

Crystal lattice energy (lattice enthalpy) is the energy released when one mole of a crystalline ionic compound is formed from its gaseous ions at infinite separation, or equivalently, the energy required to separate the lattice into gaseous ions. It is a measure of the strength of ionic bonding. Larger lattice energies indicate more stable ionic compounds.

Formula & Notation

U = −Mz₊z₋e²NA / (4πε₀r₀)(1 − 1/n); Born-Landé equation

Other Names / Synonyms: Lattice energy, ionic crystal energy, Born-Landé lattice energy, U

Properties & Characteristics

Crystal lattice energy (lattice energy, U) is the energy released when gaseous ions combine to form one mole of an ionic crystal lattice, or equivalently, the energy required to separate the lattice into gaseous ions. It is always negative (exothermic for formation). Magnitude increases with higher ion charges and smaller ionic radii. Calculated by the Born-Landé equation or estimated via Born-Haber cycles.

Uses & Applications

Lattice energy determines the stability, melting point, hardness, and solubility of ionic compounds. High lattice energy (Al₂O₃, MgO) makes compounds hard and high-melting. Lattice energy is compared with hydration energy to predict whether a compound will dissolve in water.

Safety Information

Compounds with very high lattice energy (refractory oxides like MgO, Al₂O₃) are relatively inert but require high-temperature processing (furnace work hazards). Ionic compounds with low lattice energy are more soluble and can pose environmental contamination risks.

Always consult the SDS/MSDS before handling any chemical. This information is for educational purposes only.

Key Facts

Term Crystal Lattice Energy
Formula U = −Mz₊z₋e²NA / (4πε₀r₀)(1 − 1/n); Born-Landé equation
Synonyms Lattice energy, ionic crystal energy, Born-Landé lattice energy, U

Frequently Asked Questions

Crystal lattice energy (lattice enthalpy) is the energy released when one mole of a crystalline ionic compound is formed from its gaseous ions at infinite separation, or equivalently, the energy required to separate the lattice into gaseous ions. It is a measure of the strength of ionic bonding. Larger lattice energies indicate more stable ionic compounds.

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