C

Condensation

Gas → Liquid: ΔH_cond = −ΔH_vap (exothermic)
Quick Reference
Formula / NotationGas → Liquid: ΔH_cond = −ΔH_vap (exothermic)
Also Known AsLiquefaction, dew formation, condensation reaction (step-growth polymerisation)

What is Condensation?

In chemistry, condensation refers to two related phenomena: (1) a phase change in which a vapour converts to a liquid by releasing heat, and (2) a condensation reaction (condensation polymerisation) in which two molecules combine with the elimination of a small molecule such as water. Condensation reactions form esters, peptides, and many polymers.

Formula & Notation

Gas → Liquid: ΔH_cond = −ΔH_vap (exothermic)

Other Names / Synonyms: Liquefaction, dew formation, condensation reaction (step-growth polymerisation)

Properties & Characteristics

Condensation is the phase transition from gas (vapour) to liquid, occurring when the vapour is cooled below its dew point or compressed above its saturation pressure. The process is exothermic; the latent heat of condensation equals the enthalpy of vaporisation (in magnitude). In polymerisation, condensation refers to a reaction in which monomers join with loss of a small molecule (usually H₂O).

Uses & Applications

Condensation is exploited in distillation (vapour condensed to separate mixtures), industrial refrigeration cycles, power plant steam condensers, atmospheric water collection, and dew point meteorology. Condensation polymerisation produces nylon, polyesters, and silicones.

Safety Information

Steam condensing on skin causes severe scalds (steam at 100°C carries more heat than boiling water due to latent heat). Industrial condensers must be properly insulated and drained. Condensation of reactive gases (HF, Cl₂) in lines can cause sudden, hazardous liquid release.

Always consult the SDS/MSDS before handling any chemical. This information is for educational purposes only.

Key Facts

Term Condensation
Formula Gas → Liquid: ΔH_cond = −ΔH_vap (exothermic)
Synonyms Liquefaction, dew formation, condensation reaction (step-growth polymerisation)

Frequently Asked Questions

In chemistry, condensation refers to two related phenomena: (1) a phase change in which a vapour converts to a liquid by releasing heat, and (2) a condensation reaction (condensation polymerisation) in which two molecules combine with the elimination of a small molecule such as water. Condensation reactions form esters, peptides, and many polymers.

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