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Equilibrium constant that applies to the dissociation of a comples ion into a simple ion and coordinating species (ligands).

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Crystal Field Stabilization Energy

A measure of the net energy of stabilization gained by a metal ion's nonbonding d electrons as a result of complex formation.

Salicylaldehyde

An oily, slightly water-soluble liquid, C7H6O2, having an almondlike odor: used chiefly in perfumery and in the synthesis of coumarin.

Rate-determining Step

The slowest step in a mechanism, the step that determines the overall rate of reaction.

Polydentate

Refers to ligands with more than one donor atom.

Proton

A subatomic particle having a mass of 1.0073 amu and a charge of +1, found in thew nuclei of atoms.

Native State

Refers to the occurrence of an element in an uncombined or free state in nature.

 

Alkylbenzene

A compound containing an alkyl group bonded to a benzene ring.

Differential Scanning Calorimetry (DSC)

A technique for measuring the temperature, direction, and magnitude of thermal transitions in a sample material by heating/cooling and comparing the amount of energy required to maintain its rate of temperature increase or decrease with an inert reference material under similar conditions.

Allotropic Modifications (Allotropes)

Different forms of the same element in the same physical state.

Secondary Standard

A solution that has been titrated against a primary standard. A standard solution is a secondary standard.