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Theory that accounts for the bonding and properties of metallic solids.

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Eluant or eluent

The solvent used in the process of elution, as in liquid chromatography.



Surfaces upon which oxidation and reduction half-reactions, occur in electrochemical cells.

Substitution Reaction

A reaction in which an atom or a group of atoms is replaced by another atom or group of atoms.

Diagonal Similarities

Refers to chemical similarities in the Periodic Table of elements of Period 2 to elements of Period 3 one group to the right, especially evident toward the left of the periodic table.

Molecular Orbital

An orbit resulting from overlap and mixing of atomic orbitals on different atoms. An MO belongs to the molecule as a whole.

Hydrogen Bond

A fairly strong dipole-dipole interaction (but still considerably weaker than the covalent or ionic bonds) between molecules containing hydrogen directly bonded to a small, highly electronegative atom, such as N, O, or F.


Refers to ligands with more than one donor atom.

Boyle's Law

At constant temperature the volume occupied by a definite mass of a gas is inversely proportional to the applied pressure.

Ion Product for Water

Equilibrium constant for the ionization of water, Kw = [H3O+][OH-] =1.00 x 10-14 at 25 °C.

Effective Collisons

Collision between molecules resulting in a reaction, one in which the molecules collide with proper relative orientations and sufficient energy to react.