N

Nylon 6

IUPAC: poly(caprolactam)

(C6H11NO)n Polymers & Plastics CAS 25038-54-4
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Quick Reference
Formula / Notation(C6H11NO)n
CAS Number25038-54-4
Molecular WeightVariable (polymer)
Melting Point220 °C
Boiling PointDecomposes
Density1.13 g/cm³
SolubilityInsoluble in water
Appearancewhite to off-white solid
Also Known Aspolycaprolactam; Perlon; Capron; PA 6; polyamide 6
CategoryPolymers & Plastics

What is Nylon 6?

Nylon 6 is a synthetic polyamide produced by ring-opening polymerisation of ε-caprolactam. Unlike Nylon 6,6 which is made from two monomers, Nylon 6 is produced from a single monomer. It has excellent mechanical properties, good chemical resistance, and self-lubricating properties. The repeating unit –NH(CH₂)₅CO– gives it a regular structure with strong intermolecular hydrogen bonding between amide groups.

Formula & Notation

(C6H11NO)n

IUPAC Name: poly(caprolactam)

Other Names / Synonyms: polycaprolactam; Perlon; Capron; PA 6; polyamide 6

Properties & Characteristics

Appearance: white to off-white solid (pellets or fibres). Molecular formula: (C6H11NO)n. Melting point: 220 °C. Density: 1.13 g/cm³. Tensile strength: 50–90 MPa. Solubility: insoluble in water; dissolves in concentrated sulfuric acid and formic acid. Water absorption: 2.5–3.5%.

Physical Data

PropertyValue
Melting Point220 °C
Boiling PointDecomposes
Density1.13 g/cm³
Molecular WeightVariable (polymer)
SolubilityInsoluble in water
Appearancewhite to off-white solid

Uses & Applications

Textile fibres (hosiery, sportswear). Ropes and cords. Gears, bearings, and mechanical parts. Toothbrush bristles. Fishing line and nets. Electrical connectors.

Safety Information

Low acute toxicity in solid form. Releases toxic fumes (nitrogen oxides, caprolactam) when burned. Hygroscopic — absorbs water affecting mechanical properties. Consult SDS before processing.

Always consult the SDS/MSDS before handling any chemical. This information is for educational purposes only.

Key Facts

Term Nylon 6
Formula (C6H11NO)n
CAS Number 25038-54-4
Molecular Weight Variable (polymer)
Synonyms polycaprolactam; Perlon; Capron; PA 6; polyamide 6

Frequently Asked Questions

Nylon 6 is a synthetic polyamide produced by ring-opening polymerisation of ε-caprolactam. Unlike Nylon 6,6 which is made from two monomers, Nylon 6 is produced from a single monomer. It has excellent mechanical properties, good chemical resistance, and self-lubricating properties. The repeating unit –NH(CH₂)₅CO– gives it a regular structure with strong intermolecular hydrogen bonding between amide groups.

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Editorial standards: Chemical data is sourced from peer-reviewed literature, CAS Registry, NIST WebBook, and PubChem. Safety information reflects guidance from OSHA, ECHA, and IAEA. For educational purposes only — always consult official SDS documentation and qualified professionals before handling chemicals.