N

Nylon 6,6

IUPAC: poly(hexamethylene adipamide)

(C12H22N2O2)n Polymers & Plastics CAS 32131-17-2
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Quick Reference
Formula / Notation(C12H22N2O2)n
CAS Number32131-17-2
Molecular WeightVariable (polymer)
Melting Point265 °C
Boiling PointDecomposes
Density1.14 g/cm³
SolubilityInsoluble in water
Appearancewhite to off-white solid
Also Known Aspolyamide 66; PA66; nylon 66; Zytel; Ultramid A
CategoryPolymers & Plastics

What is Nylon 6,6?

Nylon 6,6 is a polyamide produced by condensation polymerisation of hexamethylenediamine and adipic acid. The name "6,6" refers to the six carbon atoms in each monomer. It was the first commercially produced nylon, developed by DuPont in the 1930s. Compared to Nylon 6, it has a slightly higher melting point, lower moisture absorption, and greater stiffness, making it preferred for engineering applications.

Formula & Notation

(C12H22N2O2)n

IUPAC Name: poly(hexamethylene adipamide)

Other Names / Synonyms: polyamide 66; PA66; nylon 66; Zytel; Ultramid A

Properties & Characteristics

Appearance: white to off-white solid (pellets or fibres). Molecular formula: (C12H22N2O2)n. Melting point: 265 °C. Density: 1.14 g/cm³. Tensile strength: 60–85 MPa. Solubility: insoluble in water; dissolves in concentrated sulfuric acid and formic acid. Water absorption: 1.2–2.8%.

Physical Data

PropertyValue
Melting Point265 °C
Boiling PointDecomposes
Density1.14 g/cm³
Molecular WeightVariable (polymer)
SolubilityInsoluble in water
Appearancewhite to off-white solid

Uses & Applications

Automotive parts (engine covers, air intake manifolds). Electrical connectors and switch components. Textile fibres (stockings, ropes). Industrial bearings and gears. Toothbrush bristles. Parachute fabrics.

Safety Information

Low acute toxicity in solid form. Burns releasing toxic fumes. Higher processing temperatures required than Nylon 6. Consult SDS before processing.

Always consult the SDS/MSDS before handling any chemical. This information is for educational purposes only.

Key Facts

Term Nylon 6,6
Formula (C12H22N2O2)n
CAS Number 32131-17-2
Molecular Weight Variable (polymer)
Synonyms polyamide 66; PA66; nylon 66; Zytel; Ultramid A

Frequently Asked Questions

Nylon 6,6 is a polyamide produced by condensation polymerisation of hexamethylenediamine and adipic acid. The name "6,6" refers to the six carbon atoms in each monomer. It was the first commercially produced nylon, developed by DuPont in the 1930s. Compared to Nylon 6, it has a slightly higher melting point, lower moisture absorption, and greater stiffness, making it preferred for engineering applications.

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Editorial standards: Chemical data is sourced from peer-reviewed literature, CAS Registry, NIST WebBook, and PubChem. Safety information reflects guidance from OSHA, ECHA, and IAEA. For educational purposes only — always consult official SDS documentation and qualified professionals before handling chemicals.