M

Molar Conductivity

Λm = κ/c; molar conductivity decreases with √c (Kohlrausch law)
Quick Reference
Formula / NotationΛm = κ/c; molar conductivity decreases with √c (Kohlrausch law)
Also Known AsEquivalent conductance (older term), molar conductance, Λm

What is Molar Conductivity?

The conductivity of a solution containing one mole of electrolyte per liter, measured in S·cm²/mol. Molar conductivity increases with dilution for weak electrolytes (as more dissociation occurs) and approaches a limiting value (Λₘ°) for strong electrolytes at infinite dilution.

Formula & Notation

Λm = κ/c; molar conductivity decreases with √c (Kohlrausch law)

Other Names / Synonyms: Equivalent conductance (older term), molar conductance, Λm

Properties & Characteristics

Molar conductivity (Λm) is the conductivity of a solution containing one mole of electrolyte divided by the concentration: Λm = κ/c, where κ is the specific conductivity (S/m) and c is the concentration (mol/m³). For strong electrolytes, Λm decreases linearly with √c (Kohlrausch's law): Λm = Λ°m − K√c. For weak electrolytes, Λm increases significantly upon dilution (degree of dissociation increases with dilution — Ostwald's dilution law).

Uses & Applications

Molar conductivity is used in: studying electrolyte dissociation (distinguishing strong from weak electrolytes), calculating degree of dissociation and dissociation constants (Ka, Kb), measuring purity of water (conductivity), monitoring industrial electrolyte processes, and in analytical conductometry (titration end point detection).

Safety Information

No direct safety concern for the concept. High molar conductivity solutions indicate high ion concentrations, which may be corrosive (high [H⁺] in strong acid solutions, high [OH⁻] in strong base solutions). Always check pH before handling high-conductivity solutions.

Always consult the SDS/MSDS before handling any chemical. This information is for educational purposes only.

Key Facts

Term Molar Conductivity
Formula Λm = κ/c; molar conductivity decreases with √c (Kohlrausch law)
Synonyms Equivalent conductance (older term), molar conductance, Λm

Frequently Asked Questions

The conductivity of a solution containing one mole of electrolyte per liter, measured in S·cm²/mol. Molar conductivity increases with dilution for weak electrolytes (as more dissociation occurs) and approaches a limiting value (Λₘ°) for strong electrolytes at infinite dilution.

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