D

Double Salt

Double salt = two salts crystallised together; e.g., FeSO₄·(NH₄)₂SO₄·6H₂O (Mohr's salt)
Quick Reference
Formula / NotationDouble salt = two salts crystallised together; e.g., FeSO₄·(NH₄)₂SO₄·6H₂O (Mohr's salt)
Also Known AsDouble salt crystal, mixed salt, Mohr's salt type, alum type

What is Double Salt?

A salt formed by the crystallization of two different simple salts in a fixed ratio from a common solution. Double salts dissociate completely in water to yield all the constituent ions. An example is alum, KAl(SO₄)₂·12H₂O.

Formula & Notation

Double salt = two salts crystallised together; e.g., FeSO₄·(NH₄)₂SO₄·6H₂O (Mohr's salt)

Other Names / Synonyms: Double salt crystal, mixed salt, Mohr's salt type, alum type

Properties & Characteristics

A double salt is a salt formed by the crystallisation of two different salts in a fixed molar ratio. Unlike complex salts (coordination compounds), double salts completely dissociate into their constituent ions in solution (behaving as a mixture of the two simple salts). Mohr's salt [FeSO₄·(NH₄)₂SO₄·6H₂O] and alum [KAl(SO₄)₂·12H₂O] are classic double salts. Double salts differ from complex/coordination compounds.

Uses & Applications

Mohr's salt is used as a primary standard in redox titrations (more stable than FeSO₄ alone against air oxidation). Alums are used in water purification and dyeing. Double salts provide convenient crystalline forms with improved stability for analytical and industrial applications.

Safety Information

Individual hazards depend on the constituent salts. Mohr's salt contains iron(II) and ammonium sulfate — relatively low toxicity but may irritate eyes and skin. Alums are of low toxicity. Handle as general laboratory reagents with standard PPE.

Always consult the SDS/MSDS before handling any chemical. This information is for educational purposes only.

Key Facts

Term Double Salt
Formula Double salt = two salts crystallised together; e.g., FeSO₄·(NH₄)₂SO₄·6H₂O (Mohr's salt)
Synonyms Double salt crystal, mixed salt, Mohr's salt type, alum type

Frequently Asked Questions

A salt formed by the crystallization of two different simple salts in a fixed ratio from a common solution. Double salts dissociate completely in water to yield all the constituent ions. An example is alum, KAl(SO₄)₂·12H₂O.

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