D

Dextrorotatory

Optical rotation: +α (clockwise); measured by polarimetry; [α]_D > 0
Quick Reference
Formula / NotationOptical rotation: +α (clockwise); measured by polarimetry; [α]_D > 0
Also Known As(+)-rotation, d-rotation, clockwise optical rotation, dextrorotatory enantiomer

What is Dextrorotatory?

A term describing an optically active compound that rotates plane-polarized light in a clockwise direction (to the right) when viewed facing the oncoming light. Designated with a (+) or d- prefix. The opposite of levorotatory.

Formula & Notation

Optical rotation: +α (clockwise); measured by polarimetry; [α]_D > 0

Other Names / Synonyms: (+)-rotation, d-rotation, clockwise optical rotation, dextrorotatory enantiomer

Properties & Characteristics

Dextrorotatory describes a chiral compound that rotates the plane of plane-polarised light clockwise (to the right) when viewed facing the light source. Designated by (+) or d-. The magnitude of optical rotation is characterised by the specific rotation [α]_D (measured at the sodium D line, 589 nm). Dextrorotatory is a macroscopic property and does not indicate the absolute configuration (R or S) of the molecule.

Uses & Applications

Optical rotation measurements (polarimetry) are used to identify and characterise chiral compounds in pharmaceuticals, food quality control (sugar analysis by saccharimetry), biochemistry (amino acid and sugar configurations), and in monitoring asymmetric synthesis reactions.

Safety Information

Specific rotation is a physical characterisation tool; no direct safety concern. Polarimeters typically use sodium or LED light sources. Standard laboratory safety applies. For chiral drugs, the wrong enantiomer can be pharmacologically inactive or harmful (thalidomide case).

Always consult the SDS/MSDS before handling any chemical. This information is for educational purposes only.

Key Facts

Term Dextrorotatory
Formula Optical rotation: +α (clockwise); measured by polarimetry; [α]_D > 0
Synonyms (+)-rotation, d-rotation, clockwise optical rotation, dextrorotatory enantiomer

Frequently Asked Questions

A term describing an optically active compound that rotates plane-polarized light in a clockwise direction (to the right) when viewed facing the oncoming light. Designated with a (+) or d- prefix. The opposite of levorotatory.

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