P

Polybutadiene

IUPAC: poly(1,3-butadiene)

(C4H6)n Polymers & Plastics CAS 9003-17-2
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Quick Reference
Formula / Notation(C4H6)n
CAS Number9003-17-2
Molecular WeightVariable (polymer)
Melting PointGlass transition: −105 °C
Boiling PointDecomposes
Density0.90 g/cm³
SolubilityInsoluble in water
Appearancepale yellow elastomeric solid
Also Known AsBR; butadiene rubber; buna rubber
CategoryPolymers & Plastics

What is Polybutadiene?

Polybutadiene (BR) is a synthetic rubber produced by polymerisation of 1,3-butadiene. It has the highest resilience and lowest glass transition temperature (−105 °C) of any synthetic rubber, making it particularly useful in applications requiring good elasticity at low temperatures. It is primarily used as a component in tyre manufacture (blended with natural rubber and SBR) and as an impact modifier for plastics such as polystyrene and ABS.

Formula & Notation

(C4H6)n

IUPAC Name: poly(1,3-butadiene)

Other Names / Synonyms: BR; butadiene rubber; buna rubber

Properties & Characteristics

Appearance: colourless to pale yellow elastomeric solid. Molecular formula: (C4H6)n. Glass transition temperature (Tg): −105 °C. Density: 0.90 g/cm³. Tensile strength: 1–2 MPa (unfilled); up to 20 MPa (carbon black filled). Solubility: insoluble in water; soluble in aliphatic and aromatic hydrocarbons.

Physical Data

PropertyValue
Melting PointGlass transition: −105 °C
Boiling PointDecomposes
Density0.90 g/cm³
Molecular WeightVariable (polymer)
SolubilityInsoluble in water
Appearancepale yellow elastomeric solid

Uses & Applications

Tyre manufacture (primary use — ~70% of production). Golf ball cores. Impact modifier for HIPS and ABS plastics. Conveyor belts and industrial hoses. Shoe soles.

Safety Information

Low acute toxicity in cured form. Releases toxic fumes including 1,3-butadiene (probable human carcinogen) when burned. Uncured rubber can be a skin sensitiser. Consult SDS before processing.

Always consult the SDS/MSDS before handling any chemical. This information is for educational purposes only.

Key Facts

Term Polybutadiene
Formula (C4H6)n
CAS Number 9003-17-2
Molecular Weight Variable (polymer)
Synonyms BR; butadiene rubber; buna rubber

Frequently Asked Questions

Polybutadiene (BR) is a synthetic rubber produced by polymerisation of 1,3-butadiene. It has the highest resilience and lowest glass transition temperature (−105 °C) of any synthetic rubber, making it particularly useful in applications requiring good elasticity at low temperatures. It is primarily used as a component in tyre manufacture (blended with natural rubber and SBR) and as an impact modifier for plastics such as polystyrene and ABS.

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Editorial standards: Chemical data is sourced from peer-reviewed literature, CAS Registry, NIST WebBook, and PubChem. Safety information reflects guidance from OSHA, ECHA, and IAEA. For educational purposes only — always consult official SDS documentation and qualified professionals before handling chemicals.