P

Phenol-formaldehyde resin

IUPAC: phenolic resin

(C7H6O2)n Polymers & Plastics CAS 9003-35-4
Expert Written | Fact Checked | Sources Cited | AllChemicals Editorial Team
Quick Reference
Formula / Notation(C7H6O2)n
CAS Number9003-35-4
Molecular WeightVariable (polymer)
Melting PointDoes not melt (thermoset)
Boiling PointDoes not melt (thermoset)
Density1.24–1.32 g/cm³
SolubilityInsoluble in all solvents (cured)
Appearancedark brown to black hard solid
Also Known AsBakelite; phenolic resin; novolac; resole; PF resin
CategoryPolymers & Plastics

What is Phenol-formaldehyde resin?

Phenol-formaldehyde resin (PF resin), known commercially as Bakelite, was the first fully synthetic thermosetting polymer, developed by Leo Baekeland in 1907. It is produced by condensation polymerisation of phenol with formaldehyde under acidic (novolac) or alkaline (resole) conditions. Once cured, phenolic resins form a hard, thermally stable, electrically insulating crosslinked network that cannot be remelted. Bakelite revolutionised modern manufacturing as the first widely used synthetic plastic.

Formula & Notation

(C7H6O2)n

IUPAC Name: phenolic resin

Other Names / Synonyms: Bakelite; phenolic resin; novolac; resole; PF resin

Properties & Characteristics

Appearance: dark brown to black hard solid (cured). Molecular formula: complex crosslinked network. Density: 1.24–1.32 g/cm³. Heat deflection temperature: >150 °C. Flexural strength: 60–90 MPa. Solubility: insoluble in all common solvents (cured form). Dielectric strength: 10–25 kV/mm.

Physical Data

PropertyValue
Melting PointDoes not melt (thermoset)
Boiling PointDoes not melt (thermoset)
Density1.24–1.32 g/cm³
Molecular WeightVariable (polymer)
SolubilityInsoluble in all solvents (cured)
Appearancedark brown to black hard solid

Uses & Applications

Electrical insulators and switches. Printed circuit board substrate (FR-4 core layers). Brake pads and friction materials. Plywood and particleboard binder. Moulded handles and knobs. Laminate countertops and flooring.

Safety Information

Cured resin is inert and non-toxic. Uncured resin contains phenol and formaldehyde — both toxic and irritant (formaldehyde is a known carcinogen). Processing fumes require adequate ventilation. Consult SDS before use.

Always consult the SDS/MSDS before handling any chemical. This information is for educational purposes only.

Key Facts

Term Phenol-formaldehyde resin
Formula (C7H6O2)n
CAS Number 9003-35-4
Molecular Weight Variable (polymer)
Synonyms Bakelite; phenolic resin; novolac; resole; PF resin

Frequently Asked Questions

Phenol-formaldehyde resin (PF resin), known commercially as Bakelite, was the first fully synthetic thermosetting polymer, developed by Leo Baekeland in 1907. It is produced by condensation polymerisation of phenol with formaldehyde under acidic (novolac) or alkaline (resole) conditions. Once cured, phenolic resins form a hard, thermally stable, electrically insulating crosslinked network that cannot be remelted. Bakelite revolutionised modern manufacturing as the first widely used synthetic plastic.

More "P" Terms

View all "P" terms →
A B C D E F G H I J K L M N O P Q R S T U V W X Y Z
Editorial standards: Chemical data is sourced from peer-reviewed literature, CAS Registry, NIST WebBook, and PubChem. Safety information reflects guidance from OSHA, ECHA, and IAEA. For educational purposes only — always consult official SDS documentation and qualified professionals before handling chemicals.