P

Polytetrafluoroethylene

IUPAC: poly(tetrafluoroethylene)

(C2F4)n Polymers & Plastics CAS 9002-84-0
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Quick Reference
Formula / Notation(C2F4)n
CAS Number9002-84-0
Molecular WeightVariable (polymer)
Melting Point327 °C
Boiling PointDecomposes >400 °C
Density2.10–2.20 g/cm³
SolubilityInsoluble in all solvents
Appearancewhite waxy solid
Also Known AsPTFE; Teflon; fluon; halon
CategoryPolymers & Plastics

What is Polytetrafluoroethylene?

Polytetrafluoroethylene (PTFE) is a synthetic fluoropolymer consisting of tetrafluoroethylene monomers (–CF₂–CF₂–)n. It is best known under the DuPont trade name Teflon. PTFE has one of the lowest coefficients of friction of any solid material, is chemically inert to virtually all industrial chemicals and solvents, and is stable over an extremely wide temperature range. Its exceptional properties arise from the strength of the carbon–fluorine bonds and the fluorine shielding of the carbon backbone.

Formula & Notation

(C2F4)n

IUPAC Name: poly(tetrafluoroethylene)

Other Names / Synonyms: PTFE; Teflon; fluon; halon

Properties & Characteristics

Appearance: white, waxy solid. Molecular formula: (C2F4)n. Melting point: 327 °C. Density: 2.10–2.20 g/cm³. Temperature range: –200 to +260 °C (continuous use). Coefficient of friction: 0.05–0.10 (one of the lowest of any solid). Solubility: insoluble in virtually all solvents.

Physical Data

PropertyValue
Melting Point327 °C
Boiling PointDecomposes >400 °C
Density2.10–2.20 g/cm³
Molecular WeightVariable (polymer)
SolubilityInsoluble in all solvents
Appearancewhite waxy solid

Uses & Applications

Non-stick cookware coatings. Chemical-resistant gaskets, seals, and tubing. Electrical insulation for high-frequency cables. Bearings and bushings. Medical implants and vascular grafts. Plumber's thread seal tape.

Safety Information

PTFE itself is non-toxic and biologically inert. Pyrolysis above 260 °C releases toxic fluorinated gases and PFIB (perfluoroisobutylene). Avoid overheating in cookware applications. Polymer fume fever can result from breathing fumes. Consult SDS before processing.

Always consult the SDS/MSDS before handling any chemical. This information is for educational purposes only.

Key Facts

Term Polytetrafluoroethylene
Formula (C2F4)n
CAS Number 9002-84-0
Molecular Weight Variable (polymer)
Synonyms PTFE; Teflon; fluon; halon

Frequently Asked Questions

Polytetrafluoroethylene (PTFE) is a synthetic fluoropolymer consisting of tetrafluoroethylene monomers (–CF₂–CF₂–)n. It is best known under the DuPont trade name Teflon. PTFE has one of the lowest coefficients of friction of any solid material, is chemically inert to virtually all industrial chemicals and solvents, and is stable over an extremely wide temperature range. Its exceptional properties arise from the strength of the carbon–fluorine bonds and the fluorine shielding of the carbon backbone.

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Editorial standards: Chemical data is sourced from peer-reviewed literature, CAS Registry, NIST WebBook, and PubChem. Safety information reflects guidance from OSHA, ECHA, and IAEA. For educational purposes only — always consult official SDS documentation and qualified professionals before handling chemicals.