H

Halide

X⁻ (e.g., F⁻, Cl⁻, Br⁻, I⁻)
Quick Reference
Formula / NotationX⁻ (e.g., F⁻, Cl⁻, Br⁻, I⁻)
Also Known AsHalide ion, X⁻, metal halide, organic halide, hydrogen halide

What is Halide?

A binary compound formed between a halogen (F, Cl, Br, I, or At) and another element. Metal halides are typically ionic (e.g., NaCl, CaBr₂). Hydrogen halides (HF, HCl, HBr, HI) dissolve in water to form acids. Halides have important industrial and biological roles.

Formula & Notation

X⁻ (e.g., F⁻, Cl⁻, Br⁻, I⁻)

Other Names / Synonyms: Halide ion, X⁻, metal halide, organic halide, hydrogen halide

Properties & Characteristics

Halides are binary compounds of a halogen (F, Cl, Br, I, At) with a less electronegative element. Ionic halides (NaCl, CaF₂, KBr) form when metals react with halogens; covalent halides (PCl₅, CF₄, CCl₄) form between nonmetals. Metal halides range from ionic to covalent depending on metal electronegativity and charge. Fluorides and chlorides tend to be more ionic; iodides more covalent for a given metal. Halide ions are good ligands in coordination chemistry.

Uses & Applications

Halides are used as: solvents (DCM, chloroform), refrigerants (Freons, now mostly phased out), fire suppressants (halons), pesticides (organochlorines), pharmaceuticals (fluorinated drugs for metabolic stability), and industrial chemicals (PVC from vinyl chloride, polytetrafluoroethylene PTFE from TFE).

Safety Information

Many halides are toxic: CCl₄ is hepatotoxic and carcinogenic; vinyl chloride causes angiosarcoma of the liver; organochlorine pesticides are persistent bioaccumulative toxins. HF is extremely corrosive (see fluoride entry). Halogenated solvents require fume hood use and proper disposal.

Always consult the SDS/MSDS before handling any chemical. This information is for educational purposes only.

Key Facts

Term Halide
Formula X⁻ (e.g., F⁻, Cl⁻, Br⁻, I⁻)
Synonyms Halide ion, X⁻, metal halide, organic halide, hydrogen halide

Frequently Asked Questions

A binary compound formed between a halogen (F, Cl, Br, I, or At) and another element. Metal halides are typically ionic (e.g., NaCl, CaBr₂). Hydrogen halides (HF, HCl, HBr, HI) dissolve in water to form acids. Halides have important industrial and biological roles.

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