B

Buffer Solution

pH = pKa + log([A⁻]/[HA]) (Henderson-Hasselbalch equation)
Quick Reference
Formula / NotationpH = pKa + log([A⁻]/[HA]) (Henderson-Hasselbalch equation)
Also Known AspH buffer, buffer system, acid-base buffer, biological buffer

What is Buffer Solution?

A buffer solution is an aqueous solution that resists changes in pH upon addition of small amounts of acid or base. It consists of a weak acid and its conjugate base (or a weak base and its conjugate acid) in similar concentrations. Buffer solutions are critical in biological systems (blood pH ≈ 7.4), analytical chemistry, and fermentation processes.

Formula & Notation

pH = pKa + log([A⁻]/[HA]) (Henderson-Hasselbalch equation)

Other Names / Synonyms: pH buffer, buffer system, acid-base buffer, biological buffer

Properties & Characteristics

A buffer solution resists changes in pH upon addition of small amounts of acid or base. It consists of a weak acid and its conjugate base (or a weak base and its conjugate acid) in solution. Buffer capacity is greatest when [A⁻] = [HA], i.e., pH = pKa. The Henderson-Hasselbalch equation quantifies buffer pH. Biological buffers (carbonate/bicarbonate, phosphate, protein histidine residues) maintain blood pH at 7.35-7.45.

Uses & Applications

Buffer solutions are used in analytical chemistry (calibrating pH meters), biochemistry (enzyme assays, cell culture media), pharmaceutical formulations, food preservation, and industrial fermentation. The Sørensen phosphate buffer and TRIS buffer are standard laboratory reagents.

Safety Information

Buffer components themselves are generally of moderate toxicity, but concentrated strong acid or base used to prepare buffers are corrosive. Some biological buffers (e.g., TRIS) can interfere with certain assays. Always label buffer concentrations and pH; do not confuse with other solutions.

Always consult the SDS/MSDS before handling any chemical. This information is for educational purposes only.

Key Facts

Term Buffer Solution
Formula pH = pKa + log([A⁻]/[HA]) (Henderson-Hasselbalch equation)
Synonyms pH buffer, buffer system, acid-base buffer, biological buffer

Frequently Asked Questions

A buffer solution is an aqueous solution that resists changes in pH upon addition of small amounts of acid or base. It consists of a weak acid and its conjugate base (or a weak base and its conjugate acid) in similar concentrations. Buffer solutions are critical in biological systems (blood pH ≈ 7.4), analytical chemistry, and fermentation processes.

More "B" Terms

View all "B" terms →
A B C D E F G H I J K L M N O P Q R S T U V W X Y Z