A

Amphoterism

Al₂O₃ + 6HCl → 2AlCl₃ + 3H₂O; Al₂O₃ + 2NaOH + 3H₂O → 2Na[Al(OH)₄]
Quick Reference
Formula / NotationAl₂O₃ + 6HCl → 2AlCl₃ + 3H₂O; Al₂O₃ + 2NaOH + 3H₂O → 2Na[Al(OH)₄]
Also Known AsAmphiprotic behaviour (for proton transfer), amphoteric character, acid-base duality

What is Amphoterism?

Amphoterism is the property of a substance to react both as an acid and as a base. Amphoteric substances can neutralise both acids and bases. Examples include aluminium hydroxide Al(OH)₃, which dissolves in acid to form Al³⁺ ions and in strong alkali to form aluminate ions, and zinc oxide ZnO. Water is also amphoteric.

Formula & Notation

Al₂O₃ + 6HCl → 2AlCl₃ + 3H₂O; Al₂O₃ + 2NaOH + 3H₂O → 2Na[Al(OH)₄]

Other Names / Synonyms: Amphiprotic behaviour (for proton transfer), amphoteric character, acid-base duality

Properties & Characteristics

Amphoterism is the ability of a substance to react both as an acid and as a base. Amphoteric oxides and hydroxides react with strong acids to form salts and water, and with strong bases to form complex anions. Common amphoteric elements include aluminium, zinc, lead, and tin. The character arises from intermediate electronegativity and polarisation of M-O bonds.

Uses & Applications

Amphoteric aluminium oxide (alumina) is used as a catalyst support, in chromatography, and in refractory materials. Zinc oxide's amphoteric nature is exploited in galvanising and sunscreen formulations. Amphoterism is fundamental in understanding corrosion of metals like aluminium in both acidic and alkaline environments.

Safety Information

Amphoteric metal hydroxides themselves are typically low-hazard solids. The reagents used to demonstrate amphoterism (concentrated acids and strong bases like NaOH) are corrosive and require eye protection, gloves, and appropriate ventilation.

Always consult the SDS/MSDS before handling any chemical. This information is for educational purposes only.

Key Facts

Term Amphoterism
Formula Al₂O₃ + 6HCl → 2AlCl₃ + 3H₂O; Al₂O₃ + 2NaOH + 3H₂O → 2Na[Al(OH)₄]
Synonyms Amphiprotic behaviour (for proton transfer), amphoteric character, acid-base duality

Frequently Asked Questions

Amphoterism is the property of a substance to react both as an acid and as a base. Amphoteric substances can neutralise both acids and bases. Examples include aluminium hydroxide Al(OH)₃, which dissolves in acid to form Al³⁺ ions and in strong alkali to form aluminate ions, and zinc oxide ZnO. Water is also amphoteric.

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