P

Polymethyl methacrylate

IUPAC: poly(methyl 2-methylpropenoate)

(C5H8O2)n Polymers & Plastics CAS 9011-14-7
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Quick Reference
Formula / Notation(C5H8O2)n
CAS Number9011-14-7
Molecular WeightVariable (polymer)
Melting Point~160 °C (Tg: 105–115 °C)
Boiling PointDecomposes ~170 °C
Density1.17–1.20 g/cm³
SolubilityInsoluble in water
Appearanceclear glass-like solid
Also Known AsPMMA; acrylic glass; Plexiglas; Perspex; Lucite; acrylic
CategoryPolymers & Plastics

What is Polymethyl methacrylate?

Polymethyl methacrylate (PMMA), commonly known as acrylic glass or by trade names such as Plexiglas and Perspex, is a transparent thermoplastic produced by radical polymerisation of methyl methacrylate. It transmits about 92% of visible light, more than any other plastic, and has only half the weight of glass. PMMA is less impact-resistant than polycarbonate but offers superior UV resistance and optical clarity, and does not contain BPA.

Formula & Notation

(C5H8O2)n

IUPAC Name: poly(methyl 2-methylpropenoate)

Other Names / Synonyms: PMMA; acrylic glass; Plexiglas; Perspex; Lucite; acrylic

Properties & Characteristics

Appearance: clear, colourless, glass-like solid. Molecular formula: (C5H8O2)n. Glass transition temperature (Tg): 105–115 °C. Density: 1.17–1.20 g/cm³. Light transmission: ~92%. Tensile strength: 50–75 MPa. Solubility: insoluble in water; soluble in ketones, esters, aromatic solvents.

Physical Data

PropertyValue
Melting Point~160 °C (Tg: 105–115 °C)
Boiling PointDecomposes ~170 °C
Density1.17–1.20 g/cm³
Molecular WeightVariable (polymer)
SolubilityInsoluble in water
Appearanceclear glass-like solid

Uses & Applications

Optical lenses and windows. Aquarium tanks and swimming pool windows. Aircraft canopies and windshields. LED light guides. Bone cement in orthopaedic surgery. Artistic and display applications. Signage.

Safety Information

Low toxicity in solid form. Releases methyl methacrylate monomer and CO during combustion. Methyl methacrylate is a respiratory sensitiser. Susceptible to crazing with certain solvents. Consult SDS before processing.

Always consult the SDS/MSDS before handling any chemical. This information is for educational purposes only.

Key Facts

Term Polymethyl methacrylate
Formula (C5H8O2)n
CAS Number 9011-14-7
Molecular Weight Variable (polymer)
Synonyms PMMA; acrylic glass; Plexiglas; Perspex; Lucite; acrylic

Frequently Asked Questions

Polymethyl methacrylate (PMMA), commonly known as acrylic glass or by trade names such as Plexiglas and Perspex, is a transparent thermoplastic produced by radical polymerisation of methyl methacrylate. It transmits about 92% of visible light, more than any other plastic, and has only half the weight of glass. PMMA is less impact-resistant than polycarbonate but offers superior UV resistance and optical clarity, and does not contain BPA.

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Editorial standards: Chemical data is sourced from peer-reviewed literature, CAS Registry, NIST WebBook, and PubChem. Safety information reflects guidance from OSHA, ECHA, and IAEA. For educational purposes only — always consult official SDS documentation and qualified professionals before handling chemicals.