F

Formic acid

IUPAC: formic acid

CH2O2 Acids CAS 64-18-6
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Quick Reference
Formula / NotationCH2O2
CAS Number64-18-6
Molecular Weight46.025
Melting Point47.1 °F (NTP, 1992)
Boiling Point213.3 °F at 760 mmHg (NTP, 1992)
Density1.22 at 68 °F (USCG, 1999) - Denser than water; will sink
Solubilitygreater than or equal to 100 mg/mL at 70 °F (NTP, 1992)
AppearanceFormic acid appears as a colorless liquid with a pungent odor. Flash point 156 °F. Density 10.2 lb / gal. Corrosive to metals and tissue.
Also Known As64-18-6; Methanoic acid; Formylic acid; Aminic acid; Bilorin; Hydrogen carboxylic acid; Formisoton; Formira; Myrmicyl; Collo-bueglatt
CategoryAcids

What is Formic acid?

Formic acid is the simplest carboxylic acid, containing a single carbon. Occurs naturally in various sources including the venom of bee and ant stings, and is a useful organic synthetic reagent. Principally used as a preservative and antibacterial agent in livestock feed. Induces severe metabolic acidosis and ocular injury in human subjects. It has a role as a metabolite, an antibacterial agent, a solvent, a protic solvent and an astringent. It is a conjugate acid of a formate.

Formula & Notation

CH2O2

IUPAC Name: formic acid

Other Names / Synonyms: 64-18-6; Methanoic acid; Formylic acid; Aminic acid; Bilorin; Hydrogen carboxylic acid; Formisoton; Formira; Myrmicyl; Collo-bueglatt

Properties & Characteristics

Appearance: Formic acid appears as a colorless liquid with a pungent odor. Flash point 156 °F. Density 10.2 lb / gal. Corrosive to metals and tissue.. Molecular formula: CH2O2. Molecular weight: 46.025 g/mol. Boiling point: 213.3 °F at 760 mmHg (NTP, 1992). Melting point: 47.1 °F (NTP, 1992). Density: 1.22 at 68 °F (USCG, 1999) - Denser than water; will sink. Solubility: greater than or equal to 100 mg/mL at 70 °F (NTP, 1992). Vapor pressure: 35 mmHg at 68 °F ; 200 mmHg at 142.5 °F (NTP, 1992). LogP: -0.2.

Physical Data

PropertyValue
Melting Point47.1 °F (NTP, 1992)
Boiling Point213.3 °F at 760 mmHg (NTP, 1992)
Density1.22 at 68 °F (USCG, 1999) - Denser than water; will sink
Molecular Weight46.025
Solubilitygreater than or equal to 100 mg/mL at 70 °F (NTP, 1992)
AppearanceFormic acid appears as a colorless liquid with a pungent odor. Flash point 156 °F. Density 10.2 lb / gal. Corrosive to metals and tissue.

Uses & Applications

Used in industrial chemical synthesis, fertilizer production, battery electrolytes, metal processing, and laboratory acid-base reactions.

Safety Information

Corrosive. Causes severe burns to skin, eyes, and respiratory tract. Wear appropriate PPE including gloves, goggles, and lab coat. Consult SDS before use.

Always consult the SDS/MSDS before handling any chemical. This information is for educational purposes only.

Key Facts

Term Formic acid
Formula CH2O2
CAS Number 64-18-6
Molecular Weight 46.025
Category Acids
Synonyms 64-18-6; Methanoic acid; Formylic acid; Aminic acid; Bilorin; Hydrogen carboxylic acid; Formisoton; Formira; Myrmicyl; Collo-bueglatt

Frequently Asked Questions

Formic acid is the simplest carboxylic acid, containing a single carbon. Occurs naturally in various sources including the venom of bee and ant stings, and is a useful organic synthetic reagent. Principally used as a preservative and antibacterial agent in livestock feed. Induces severe metabolic acidosis and ocular injury in human subjects. It has a role as a metabolite, an antibacterial agent, a solvent, a protic solvent and an astringent. It is a conjugate acid of a formate.

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Editorial standards: Chemical data is sourced from peer-reviewed literature, CAS Registry, NIST WebBook, and PubChem. Safety information reflects guidance from OSHA, ECHA, and IAEA. For educational purposes only — always consult official SDS documentation and qualified professionals before handling chemicals.