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Induced Dipole

Induced dipole: α × E (α = polarisability; E = electric field)
Quick Reference
Formula / NotationInduced dipole: α × E (α = polarisability; E = electric field)
Also Known AsTemporary dipole, instantaneous dipole, polarisation-induced dipole

What is Induced Dipole?

A temporary dipole created in a nonpolar molecule by a nearby polar molecule or ion. The electric field of the polar species distorts the electron cloud of the nonpolar molecule. Induced dipoles give rise to London dispersion forces between all molecules.

Formula & Notation

Induced dipole: α × E (α = polarisability; E = electric field)

Other Names / Synonyms: Temporary dipole, instantaneous dipole, polarisation-induced dipole

Properties & Characteristics

An induced dipole is a temporary separation of charge in a normally nonpolar atom or molecule, caused by the approach of a nearby permanent dipole or ion, which distorts the electron cloud. The magnitude depends on the polarisability (α) of the molecule and the strength of the inducing field. Larger, more diffuse electron clouds (heavier atoms) have higher polarisability and form larger induced dipoles. Induced dipole-induced dipole interactions are London dispersion forces.

Uses & Applications

Induced dipoles are central to understanding: London dispersion forces (dominant for large nonpolar molecules like I₂, hydrocarbons), ion-induced dipole interactions (governing solvation of ions in nonpolar media and binding of metal ions to π systems in coordination chemistry), and the origin of van der Waals attractions between noble gas atoms.

Safety Information

No direct safety concern. Understanding induced dipoles helps explain why heavier nonpolar chemicals (higher polarisability) are retained longer in reversed-phase chromatography and have higher boiling points. Heavier noble gases (Ar, Kr, Xe) have larger induced dipoles and stronger narcotic properties at high concentrations.

Always consult the SDS/MSDS before handling any chemical. This information is for educational purposes only.

Key Facts

Term Induced Dipole
Formula Induced dipole: α × E (α = polarisability; E = electric field)
Synonyms Temporary dipole, instantaneous dipole, polarisation-induced dipole

Frequently Asked Questions

A temporary dipole created in a nonpolar molecule by a nearby polar molecule or ion. The electric field of the polar species distorts the electron cloud of the nonpolar molecule. Induced dipoles give rise to London dispersion forces between all molecules.

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