S

Sodium azide

IUPAC: sodium azide

N3Na Inorganic Compounds CAS 26628-22-8
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Quick Reference
Formula / NotationN3Na
CAS Number26628-22-8
Molecular Weight65.010
Melting PointDecomposes at 527 °F to sodium and nitrogen (EPA, 1998)
Boiling PointDecomposes in vacuum (EPA, 1998)
Density1.846 at 68 °F (EPA, 1998) - Denser than water; will sink
Solubility50 to 100 mg/mL at 72 °F (NTP, 1992)
AppearanceSodium azide appears as a colorless crystalline solid. Density 1.85 g / cm3. Burns in air and may explode if large quantities are involved. Toxic by ingestion. Toxic oxides of nitrogen are produced...
Also Known As26628-22-8; Azide, sodium; Natriumazid; Hydrazoic acid sodium salt; Azoture de sodium; Nemazyd; Kazoe; Sodium, azoture de; Natriummazide; hydrazoic acid, sodium salt
CategoryInorganic Compounds

What is Sodium azide?

Sodium azide is the sodium salt of hydrogen azide (hydrazoic acid). It has a role as a mitochondrial respiratory-chain inhibitor, a mutagen, an antibacterial agent and an explosive. It contains an azide anion.

Formula & Notation

N3Na

IUPAC Name: sodium azide

Other Names / Synonyms: 26628-22-8; Azide, sodium; Natriumazid; Hydrazoic acid sodium salt; Azoture de sodium; Nemazyd; Kazoe; Sodium, azoture de; Natriummazide; hydrazoic acid, sodium salt

Properties & Characteristics

Appearance: Sodium azide appears as a colorless crystalline solid. Density 1.85 g / cm3. Burns in air and may explode if large quantities are involved. Toxic by ingestion. Toxic oxides of nitrogen are produced.... Molecular formula: N3Na. Molecular weight: 65.010 g/mol. Boiling point: Decomposes in vacuum (EPA, 1998). Melting point: Decomposes at 527 °F to sodium and nitrogen (EPA, 1998). Density: 1.846 at 68 °F (EPA, 1998) - Denser than water; will sink. Solubility: 50 to 100 mg/mL at 72 °F (NTP, 1992). Vapor pressure: 1 Pa at 20 °C.

Physical Data

PropertyValue
Melting PointDecomposes at 527 °F to sodium and nitrogen (EPA, 1998)
Boiling PointDecomposes in vacuum (EPA, 1998)
Density1.846 at 68 °F (EPA, 1998) - Denser than water; will sink
Molecular Weight65.010
Solubility50 to 100 mg/mL at 72 °F (NTP, 1992)
AppearanceSodium azide appears as a colorless crystalline solid. Density 1.85 g / cm3. Burns in air and may explode if large quantities are involved. Toxic by ingestion. Toxic oxides of nitrogen are produced...

Uses & Applications

Used in industrial processes, materials science, semiconductor manufacture, ceramics, or as a catalyst.

Safety Information

May be corrosive, toxic, or an oxidising agent. Handle in well-ventilated area. Consult SDS before use.

Always consult the SDS/MSDS before handling any chemical. This information is for educational purposes only.

Key Facts

Term Sodium azide
Formula N3Na
CAS Number 26628-22-8
Molecular Weight 65.010
Synonyms 26628-22-8; Azide, sodium; Natriumazid; Hydrazoic acid sodium salt; Azoture de sodium; Nemazyd; Kazoe; Sodium, azoture de; Natriummazide; hydrazoic acid, sodium salt

Frequently Asked Questions

Sodium azide is the sodium salt of hydrogen azide (hydrazoic acid). It has a role as a mitochondrial respiratory-chain inhibitor, a mutagen, an antibacterial agent and an explosive. It contains an azide anion.

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Editorial standards: Chemical data is sourced from peer-reviewed literature, CAS Registry, NIST WebBook, and PubChem. Safety information reflects guidance from OSHA, ECHA, and IAEA. For educational purposes only — always consult official SDS documentation and qualified professionals before handling chemicals.