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Orbital Hybridization

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Also Known AsHybridization, orbital mixing, hybrid orbital formation, sp hybridization

What is Orbital Hybridization?

Orbital hybridization is the mixing of atomic orbitals of similar energies to form new hybrid orbitals with different shapes and energies, better suited for bonding. Hybridization explains molecular geometry, bond angles, and bonding in many molecules. Common hybridizations include sp (linear, 180°), sp² (trigonal planar, 120°), sp³ (tetrahedral, 109.5°), sp³d (trigonal bipyramidal), and sp³d² (octahedral).

Properties & Characteristics

sp: mixing s + p → 2 linear hybrid orbitals. Bond angle: 180°. Example: BeH₂, CO₂, alkynes. sp²: s + 2p → 3 trigonal planar. Bond angle: 120°. Example: BF₃, ethylene. sp³: s + 3p → 4 tetrahedral. Bond angle: 109.5°. Example: CH₄, NH₃, H₂O. sp³d: 5 trigonal bipyramidal. sp³d²: 6 octahedral.

Uses & Applications

Explaining and predicting molecular geometry. Understanding bond angles and molecular shapes. Predicting reactivity (sp³ vs sp² carbon reactivity). Drug design (geometry affects binding). Polymer chain flexibility. Protein and enzyme structure. Spectroscopy interpretation.

Safety Information

Theoretical concept — no direct safety concerns.

Always consult the SDS/MSDS before handling any chemical. This information is for educational purposes only.

Key Facts

Term Orbital Hybridization
Synonyms Hybridization, orbital mixing, hybrid orbital formation, sp hybridization

Frequently Asked Questions

Orbital hybridization is the mixing of atomic orbitals of similar energies to form new hybrid orbitals with different shapes and energies, better suited for bonding. Hybridization explains molecular geometry, bond angles, and bonding in many molecules. Common hybridizations include sp (linear, 180°), sp² (trigonal planar, 120°), sp³ (tetrahedral, 109.5°), sp³d (trigonal bipyramidal), and sp³d² (octahedral).

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