R

Rate Constant

Rate = k[A]^m[B]^n; k = A·e^(-Ea/RT)
Quick Reference
Formula / NotationRate = k[A]^m[B]^n; k = A·e^(-Ea/RT)
Also Known AsRate coefficient, specific rate constant, k value

What is Rate Constant?

The proportionality constant (k) in a rate law relating reaction rate to reactant concentrations. It depends on temperature (Arrhenius equation: k = Ae^(-Ea/RT)) but not on concentration. Units depend on the overall order of the reaction.

Formula & Notation

Rate = k[A]^m[B]^n; k = A·e^(-Ea/RT)

Other Names / Synonyms: Rate coefficient, specific rate constant, k value

Properties & Characteristics

The rate constant k is a proportionality constant in the rate law that relates reaction rate to reactant concentrations. It is specific to a given reaction at a given temperature and is independent of concentration. The units of k depend on the overall reaction order. The rate constant increases with temperature according to the Arrhenius equation.

Uses & Applications

Rate constants are used to design chemical reactors and optimise industrial processes. They are essential in pharmacokinetics for modelling drug metabolism. Rate constants help predict the shelf life of chemicals and pharmaceuticals.

Safety Information

Reactions with very large rate constants proceed rapidly and may be explosive or highly exothermic, requiring careful handling. Rate constant data guides safe operating conditions for chemical processes.

Always consult the SDS/MSDS before handling any chemical. This information is for educational purposes only.

Key Facts

Term Rate Constant
Formula Rate = k[A]^m[B]^n; k = A·e^(-Ea/RT)
Synonyms Rate coefficient, specific rate constant, k value

Frequently Asked Questions

The proportionality constant (k) in a rate law relating reaction rate to reactant concentrations. It depends on temperature (Arrhenius equation: k = Ae^(-Ea/RT)) but not on concentration. Units depend on the overall order of the reaction.

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