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Photochemistry

A + hν → A* → products; Φ = products/photons
Quick Reference
Formula / NotationA + hν → A* → products; Φ = products/photons
Also Known AsPhotochemistry, photochemical reaction, photochemical process, light-induced chemistry

What is Photochemistry?

The branch of chemistry concerned with chemical reactions and physical processes initiated by the absorption of light (photons). Photochemical reactions include photosynthesis, photography, ozone formation, and vision. The energy of absorbed photons drives the reaction.

Formula & Notation

A + hν → A* → products; Φ = products/photons

Other Names / Synonyms: Photochemistry, photochemical reaction, photochemical process, light-induced chemistry

Properties & Characteristics

Photochemistry is the branch of chemistry studying chemical reactions initiated by the absorption of light (photons). When a molecule absorbs a photon, it reaches an electronically excited state, which may undergo: fluorescence (emission, return to ground state), photodissociation (bond cleavage), photoisomerisation (e.g., cis-trans isomerisation), energy transfer, or electron transfer (photoredox). The quantum yield (Φ) measures the efficiency of a photochemical process: Φ = mol of product / mol of photons absorbed.

Uses & Applications

Photochemistry drives: photosynthesis (solar energy conversion), vision (11-cis-retinal photoisomerisation to all-trans), photography (AgBr photodecomposition), sunscreen design (absorb UV to protect skin), photodynamic therapy (PDT for cancer), organic solar cells (photoexcited charge separation), and ozone chemistry (stratospheric photolysis of O₃ and CFCs).

Safety Information

UV photons used in photochemical reactions can cause skin burns and eye damage (photokeratitis). High-power UV lamps, excimer lasers, and broad-spectrum UV sources require appropriate enclosures and UV-protective eyewear. Some photochemical intermediates (singlet oxygen, reactive radicals) are toxic to biological tissue.

Always consult the SDS/MSDS before handling any chemical. This information is for educational purposes only.

Key Facts

Term Photochemistry
Formula A + hν → A* → products; Φ = products/photons
Synonyms Photochemistry, photochemical reaction, photochemical process, light-induced chemistry

Frequently Asked Questions

The branch of chemistry concerned with chemical reactions and physical processes initiated by the absorption of light (photons). Photochemical reactions include photosynthesis, photography, ozone formation, and vision. The energy of absorbed photons drives the reaction.

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