P

Paramagnetic

χ_m > 0; unpaired electrons; μ = √(n(n+2)) BM (n = unpaired electrons)
Quick Reference
Formula / Notationχ_m > 0; unpaired electrons; μ = √(n(n+2)) BM (n = unpaired electrons)
Also Known AsParamagnetic property, magnetic susceptibility χ>0, paramagnetism

What is Paramagnetic?

Describes materials with one or more unpaired electrons that are weakly attracted to a magnetic field. Paramagnetic species align their unpaired electron spins with an external field. Oxygen (O₂) is paramagnetic, which was correctly predicted by molecular orbital theory.

Formula & Notation

χ_m > 0; unpaired electrons; μ = √(n(n+2)) BM (n = unpaired electrons)

Other Names / Synonyms: Paramagnetic property, magnetic susceptibility χ>0, paramagnetism

Properties & Characteristics

Paramagnetism is the property of a substance that has one or more unpaired electrons, resulting in a net magnetic moment. Paramagnetic substances are weakly attracted to external magnetic fields. The magnetic moment (μ) in Bohr magnetons (BM) is μ = √(n(n+2)), where n is the number of unpaired electrons. Paramagnetism is temperature-dependent (Curie's law: χ ∝ 1/T). Examples: O₂ (2 unpaired e⁻, confirmed by MO theory), Cu²⁺, Fe³⁺, Mn²⁺ (5 unpaired e⁻).

Uses & Applications

Paramagnetic properties are used in: determining the number of unpaired electrons in transition metal complexes (magnetic susceptibility measurements), designing MRI contrast agents (Gd³⁺ with 7 unpaired e⁻ gives strong paramagnetic relaxation enhancement), EPR/ESR spectroscopy (detecting paramagnetic species in catalytic cycles), and in understanding oxygen's reactivity.

Safety Information

Strongly paramagnetic substances in bulk (Fe, Ni, Co) are attracted by MRI magnets and can become dangerous projectiles. Liquid oxygen (paramagnetic) is attracted to magnetic fields. Paramagnetic contrast agents (Gd³⁺) carry nephrotoxicity risk and can cause NSF in renal patients.

Always consult the SDS/MSDS before handling any chemical. This information is for educational purposes only.

Key Facts

Term Paramagnetic
Formula χ_m > 0; unpaired electrons; μ = √(n(n+2)) BM (n = unpaired electrons)
Synonyms Paramagnetic property, magnetic susceptibility χ>0, paramagnetism

Frequently Asked Questions

Describes materials with one or more unpaired electrons that are weakly attracted to a magnetic field. Paramagnetic species align their unpaired electron spins with an external field. Oxygen (O₂) is paramagnetic, which was correctly predicted by molecular orbital theory.

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