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Lanthanides

[Xe]4f^n6s²
Quick Reference
Formula / Notation[Xe]4f^n6s²
Also Known AsRare earth elements (partially overlapping), 4f elements, lanthanoid series

What is Lanthanides?

The series of 14 elements (cerium to lutetium, atomic numbers 58-71) in which the 4f subshell is progressively filled. Also called rare earth elements. Lanthanides have similar chemical properties due to the shielding of the 4f electrons. Used in magnets, catalysts, and phosphors.

Formula & Notation

[Xe]4f^n6s²

Other Names / Synonyms: Rare earth elements (partially overlapping), 4f elements, lanthanoid series

Properties & Characteristics

Lanthanides are the 15 elements from lanthanum (La, Z=57) to lutetium (Lu, Z=71), in which the 4f electron subshell is progressively filled. They are characterised by: dominant +3 oxidation state, very similar ionic radii (lanthanide contraction due to poor f-electron shielding), similar chemistry across the series, and large coordination numbers (6-12). They include both stable (all except Pm) and radioactive (Pm only) elements. Many emit visible luminescence.

Uses & Applications

Lanthanides are used in: high-strength permanent magnets (Nd₂Fe₁₄B neodymium magnets), phosphors in LED lighting and flat panel displays (Eu³⁺ red, Tb³⁺ green), MRI contrast agents (Gd³⁺ complexes), lasers (Nd:YAG for surgery, Er:YAG for dentistry), catalytic converters, and in petroleum cracking catalysts.

Safety Information

Lanthanide compounds have low-to-moderate toxicity. Gadolinium used in MRI contrast agents can cause nephrogenic systemic fibrosis (NSF) in patients with severe renal impairment. Cerium compounds are mild irritants. Mining of lanthanide ores generates radioactive thorium waste.

Always consult the SDS/MSDS before handling any chemical. This information is for educational purposes only.

Key Facts

Term Lanthanides
Formula [Xe]4f^n6s²
Synonyms Rare earth elements (partially overlapping), 4f elements, lanthanoid series

Frequently Asked Questions

The series of 14 elements (cerium to lutetium, atomic numbers 58-71) in which the 4f subshell is progressively filled. Also called rare earth elements. Lanthanides have similar chemical properties due to the shielding of the 4f electrons. Used in magnets, catalysts, and phosphors.

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