F

First Ionisation Energy

IE₁: M(g) → M⁺(g) + e⁻; increases across period, decreases down group
Quick Reference
Formula / NotationIE₁: M(g) → M⁺(g) + e⁻; increases across period, decreases down group
Also Known AsFirst ionisation potential, IE₁, first IP, IE1

What is First Ionisation Energy?

The energy required to remove the outermost electron from a neutral gaseous atom, forming a +1 ion. Ionization energies generally increase across a period and decrease down a group. Discontinuities in ionization energy trends provide evidence for electron shell structure.

Formula & Notation

IE₁: M(g) → M⁺(g) + e⁻; increases across period, decreases down group

Other Names / Synonyms: First ionisation potential, IE₁, first IP, IE1

Properties & Characteristics

The first ionisation energy (IE₁) is the minimum energy required to remove the outermost electron from a neutral gaseous atom to form a gaseous cation: M(g) → M⁺(g) + e⁻. It is always endothermic (positive). IE₁ increases across a period (increasing nuclear charge, same shielding) and decreases down a group (increasing atomic radius, more shielding). Noble gases have the highest IE₁ in their periods; alkali metals have the lowest.

Uses & Applications

IE₁ values predict metal reactivity, explain periodic trends in metallic/non-metallic character, guide prediction of accessible oxidation states, and are key data in Born-Haber cycle calculations. Anomalies in IE₁ trends (e.g., O < N in Period 2) are explained by electron pair repulsion in p orbitals.

Safety Information

Elements with very low IE₁ (alkali metals: Na, K, Li) react violently with water and air. Their extreme reactivity is a consequence of easily removing their single valence electron. Store under mineral oil or inert gas; never expose to water.

Always consult the SDS/MSDS before handling any chemical. This information is for educational purposes only.

Key Facts

Term First Ionisation Energy
Formula IE₁: M(g) → M⁺(g) + e⁻; increases across period, decreases down group
Synonyms First ionisation potential, IE₁, first IP, IE1

Frequently Asked Questions

The energy required to remove the outermost electron from a neutral gaseous atom, forming a +1 ion. Ionization energies generally increase across a period and decrease down a group. Discontinuities in ionization energy trends provide evidence for electron shell structure.

More "F" Terms

View all "F" terms →
A B C D E F G H I J K L M N O P Q R S T U V W X Y Z