E

Equivalents

Equiv. wt = M/n; n = H⁺, OH⁻, or e⁻ per formula unit
Quick Reference
Formula / NotationEquiv. wt = M/n; n = H⁺, OH⁻, or e⁻ per formula unit
Also Known AsEquivalent weight, gram equivalent, normality (related), mEq, chemical equivalent

What is Equivalents?

A unit expressing the reacting capacity of a substance. One equivalent of an acid contains one mole of H⁺ ions; one equivalent of a base contains one mole of OH⁻ ions. Equivalent weight = molar mass divided by the number of equivalents per mole.

Formula & Notation

Equiv. wt = M/n; n = H⁺, OH⁻, or e⁻ per formula unit

Other Names / Synonyms: Equivalent weight, gram equivalent, normality (related), mEq, chemical equivalent

Properties & Characteristics

In chemistry, an equivalent (or equivalent weight) is the amount of a substance that reacts with, displaces, or is otherwise equivalent to 1 mole of hydrogen ions (H⁺) or electrons. Normality (N) = equivalents per litre. Equivalent weight = molar mass / n (where n = number of reactive H⁺, OH⁻, or electrons per formula unit). Modern chemistry prefers moles and molarity, but normality/equivalents are still used in some titrimetric and clinical analyses.

Uses & Applications

Equivalents are used in acid-base titrations (defining normality of acid/base solutions), redox titrations (electron-equivalents), and some clinical analyses (mEq/L for electrolyte concentrations in blood: e.g., Na⁺ 135-145 mEq/L). Ion exchange capacity of resins is expressed in meq/g.

Safety Information

No direct safety concern for the concept. Calculating in equivalents rather than moles can lead to errors if the number of reactive groups (n) is misidentified. Double-check n values for polyprotic acids, polyvalent metal ions, and multi-electron redox changes.

Always consult the SDS/MSDS before handling any chemical. This information is for educational purposes only.

Key Facts

Term Equivalents
Formula Equiv. wt = M/n; n = H⁺, OH⁻, or e⁻ per formula unit
Synonyms Equivalent weight, gram equivalent, normality (related), mEq, chemical equivalent

Frequently Asked Questions

A unit expressing the reacting capacity of a substance. One equivalent of an acid contains one mole of H⁺ ions; one equivalent of a base contains one mole of OH⁻ ions. Equivalent weight = molar mass divided by the number of equivalents per mole.

More "E" Terms

View all "E" terms →
A B C D E F G H I J K L M N O P Q R S T U V W X Y Z