E

Endothermic Reaction

ΔH > 0 (heat absorbed); H_products > H_reactants
Quick Reference
Formula / NotationΔH > 0 (heat absorbed); H_products > H_reactants
Also Known AsHeat-absorbing reaction, endothermal reaction, endergonic (for free energy)

What is Endothermic Reaction?

A chemical reaction that absorbs heat energy from the surroundings, causing the temperature of the surroundings to decrease. The enthalpy change (ΔH) is positive. Examples include dissolving ammonium nitrate in water and photosynthesis.

Formula & Notation

ΔH > 0 (heat absorbed); H_products > H_reactants

Other Names / Synonyms: Heat-absorbing reaction, endothermal reaction, endergonic (for free energy)

Properties & Characteristics

An endothermic reaction is one in which energy (usually as heat) is absorbed from the surroundings, so the system's enthalpy increases (ΔH > 0). The reactants have lower enthalpy than the products. Endothermic reactions make the surroundings cool. Examples: thermal decomposition of calcium carbonate (CaCO₃ → CaO + CO₂, ΔH = +178 kJ/mol), dissolving ammonium nitrate (ΔH > 0), photosynthesis.

Uses & Applications

Endothermic reactions are used in instant cold packs (NH₄NO₃ dissolving in water), endothermic shock absorbers, endothermic smelting operations (reduction of metal oxides), and in industrial cracking of hydrocarbons (steam cracking of naphtha to ethylene).

Safety Information

Endothermic reactions can cool reaction mixtures significantly, which can affect reactant solubility and potentially cause product precipitation. Heat-consuming reactions may need continuous energy input to maintain adequate rates. Some endothermic reactions (photochemical) proceed only under irradiation conditions.

Always consult the SDS/MSDS before handling any chemical. This information is for educational purposes only.

Key Facts

Term Endothermic Reaction
Formula ΔH > 0 (heat absorbed); H_products > H_reactants
Synonyms Heat-absorbing reaction, endothermal reaction, endergonic (for free energy)

Frequently Asked Questions

A chemical reaction that absorbs heat energy from the surroundings, causing the temperature of the surroundings to decrease. The enthalpy change (ΔH) is positive. Examples include dissolving ammonium nitrate in water and photosynthesis.

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