W

Water Equivalent

W_eq = specific heat × mass; W_eq(calorimeter) = mc
Quick Reference
Formula / NotationW_eq = specific heat × mass; W_eq(calorimeter) = mc
Also Known AsCalorimeter water equivalent, heat capacity of calorimeter, calorimeter constant

What is Water Equivalent?

The mass of water that would absorb the same amount of heat as a calorimeter for a given temperature rise. Used to correct for heat absorbed by the calorimeter itself in calorimetric measurements. Determined by calibration with a substance of known heat capacity.

Formula & Notation

W_eq = specific heat × mass; W_eq(calorimeter) = mc

Other Names / Synonyms: Calorimeter water equivalent, heat capacity of calorimeter, calorimeter constant

Properties & Characteristics

The water equivalent of a calorimeter is the mass of water that would absorb the same amount of heat as the calorimeter itself for the same temperature rise. It is determined by calibration using a known amount of heat. This value accounts for the heat absorbed by the calorimeter walls and is added to the water mass in heat capacity calculations. It has units of grams or kilograms.

Uses & Applications

The water equivalent is used in bomb calorimetry and solution calorimetry calculations to correct for heat absorbed by the instrument. It enables accurate determination of enthalpies of combustion and reaction. It is a calibration parameter in precise thermochemical measurements.

Safety Information

Water equivalent determination involves calibration experiments that may use explosive or flammable substances in bomb calorimeters. Appropriate safety procedures for calorimetry apply.

Always consult the SDS/MSDS before handling any chemical. This information is for educational purposes only.

Key Facts

Term Water Equivalent
Formula W_eq = specific heat × mass; W_eq(calorimeter) = mc
Synonyms Calorimeter water equivalent, heat capacity of calorimeter, calorimeter constant

Frequently Asked Questions

The mass of water that would absorb the same amount of heat as a calorimeter for a given temperature rise. Used to correct for heat absorbed by the calorimeter itself in calorimetric measurements. Determined by calibration with a substance of known heat capacity.

More "W" Terms

View all "W" terms →
A B C D E F G H I J K L M N O P Q R S T U V W X Y Z